I want to know two things

1. Can I select with this mod rel=nofollow links for certain links around the web?
For example to all /profile links in the menu and all around.

2. Can I select noindex,dofollow for certain pages with this mod?

Regards

1. That isn't built in (to manually adjust them); however, the mod automatically inserts nofollow links to certain hyperlinks that require it and don't have the attribute by default.

2. Just like 1, it's automatically done by the mod where it's required.